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Definition of afternoon : The part of the day which follows noon, between noon and evening.

Synonyms:

siesta hour, all right, day, afterlife, midday, daytime, cocktail hour, bedtime, PM, daylight, good evening, afternoons, hello, good day, good afternoon, eve, teatime, even, autumn, hiya, hi, good morning, pleased to meet you, darkness, evening, postmeridian, lunchtime, hey

Usage examples:

• It was three in the afternoon. - "Love Me Little, Love Me Long", Charles Reade Edition: 10 Language: English.
• No, you're not, for you're going back with me this afternoon. - "Harley Greenoak's Charge", Bertram Mitford.
• Not this afternoon- the doctor is coming. - "The Fruit of the Tree", Edith Wharton.